Linear viscoelasticity of emulsions : I. The effect of an interfacial film on the dynamic viscosity of nondilute emulsions

The dynamic viscosity of nondilute monodisperse emulsions is calculated by using a cell model. Two possibilities for describing the mechanical properties of the interfacial film between the internal and the external phase are considered: (A) the film is assigned a two-dimensional linear viscoelastic behavior and (B) the film is treated as a shell with finite thickness containing a Newtonian liquid. The resulting expressions for the dynamic viscosity show that model B has two relaxation times and model A has at least two or more. If a Voigt-Kelvin model is used to describe the interfacial rheology, model A will also have just two relaxation times. The results obtained may be used to interpret measurements on emulsions in terms of microscopic parameters of these emulsions

Linear viscoelasticity of emulsions : II. Measurements of the linear viscoelastic behavior of emulsions in the kilohertz range

Linear viscoelasticity of emulsions in shear deformation in the kilohertz range is demonstrated experimentally. In order to avoid complications due to inertia effects, emulsions with small droplet sizes are studied. The preliminary measurements are interpreted as being the result of droplet deformations. If this interpretation is correct, measurements of the dynamic viscosity of emulsions may be used to obtain information about the mechanical properties of the interfacial layer between droplets and the continuous phase. In particular, the evaluation of the interfacial tension of emulsion droplets from bulk properties might be possible using this technique

Broad-band X-ray measurements of the black hole candidate XTE J1908+094

XTE J1908+094 is an X-ray transient that went into outburst in February 2002. After two months it reached a 2-250 keV peak flux of 1 to 2 X 10-8 erg/s/cm2. Circumstantial evidence points to an accreting galactic black hole as the origin of the the X-radiation: pulsations nor thermonuclear flashes were detected that would identify a neutron star and the spectrum was unusually hard for a neutron star at the outburst onset. We report on BeppoSAX and RXTE All Sky Monitor observations of the broad-band spectrum of XTE J1908+094. The spectrum is consistent with a model consisting of a Comptonization component by a ~40 keV plasma (between 2 and 60 keV this component can be approximated by a power law with a photon index of 1.9 to 2.1), a multicolor accretion disk blackbody component with a temperature just below 1 keV and a broad emission line at about 6 keV. The spectrum is heavily absorbed by cold interstellar matter with an equivalent hydrogen column density of 2.5 X 10+22 cm-2, which makes it difficult to study the black body component in detail. The black body component exhibits strong evolution about 6 weeks into the outburst. Two weeks later this is followed by a swift decay of the power law component. The broadness of the 6 keV feature may be due to relativistic broadening or Compton scattering of a narrow Fe-K line.Comment: Accepted for publication in Astronomy & Astrophysic

Calculation of the effect of inertia on the dynamic viscosity of dilute emulsions in a pure straining motion

The dynamic viscosity of a dilute emulsion is calculated for a pure straining motion. The emulsion consists of almost spherical drops of a Newtonian fluid immersed in another Newtonian fluid. The oscillating velocity field of the flow is derived from the Navier-Stokes equation, in which the linear inertia term is included, whereas the non-linear one is neglected. The dynamic viscosity is determined with the aid of a cell model. The results are calculated numerically and typical results are presented graphically. The influence of inertia on the dynamic viscosity appears to be appreciable. Special cases presented in the literature, frequency or density zero and rigid spheres, are confirmed